What I meant to say is that EURCZK will have different dynamics than EURMAD, say, once it is floating, because CZK has a different economy, trading parters, and central banking from MAD - so simply looking at EURCZK without making some adjustment for it being a different currency cross would be incomplete. The level of volatility of EURMAD will just be different from EURCZK, so you have to make a reasonable adjustment up or down from EURCZK volatility levels in making your estimate. I was suggesting trying to find a reasonable EUR/CCY proxy that is currently liquidly traded, which you feel would more closely resemble what you think EURMAD given CCY's more similar dynamics to MAD than CZK. Then you could make an argument that after the jump, the volatility will be EURCZK+/-EURCCY volatility.
In any case, I apologize for not having a deeper background in MAD. I just looked it up and it seems it's more of a soft peg in the form of a managed basket of 60% EUR and 40% USD. That's more similar to what Russia had for RUB, which was a managed basket of 45% EUR and 55% USD, which they abolished in 2014. Russia abolished it in part because the shift in the price of crude oil is a more important factor in its terms of trade than either of those other two currencies, and the weakening of the price of oil meant Russia would have had a really hard time managing its currency reserves under a soft peg. The move really just meant oil became a stronger factor in determining currency movements, as well as political moves like US sanctions following the invasion of Crimea, so RUB simply became a more volatile currency but without really any crazy jump to speak of. Morocco is going to be a bit different. First of all, the it looks like 75% of its foreign denominated debt is in EUR and the balance mostly USD, and its export market shares look similar. That would usually mean a good basket for them to be smoothing is 75% EUR and 25% USD, and it did used to do that with a basket of 80% EUR and 20% USD. However, it moved to its current 60%/40% weighting to allow for a global factor from the big USD move. The important thing is that they've already done that as a step toward free floating. I haven't looked into the trend in central bank reserves - I'll leave that to you - but barring a large trend of declining FX reserves, I would estimate that the volatility of MAD after the free float will look fairly similar to the volatility of MAD today. It's fairly intuitive to say that the volatility purely due to a free float will result in a greater than or equal to volatility of the currency today, but the effect shouldn't be enormous given its largest two components of EUR and USD are already in the price. However, if there has been a large trend in FX reserves declining even after the basket was revised to 60%/40%, then you could see a faster depreciation in the MAD and a significantly higher level of volatility going forward. No stochastic model will help you find an answer to this sort of question. You can try looking up complex macroeconomic models for forecasting floating exchange rate volatility following a managed float, but I wouldn't put much faith into that either - if literature even exists on the subject.